EAN: 9783319302904

DIGITAL SIMULATION IN ELECTROCHEMISTRY - DIETER...

This book explains how the partial differential equations (pdes) in electroanalytical chemistry
can be solved numerically. It guides the reader through the topic in a very didactic way  by
first introducing and discussing the basic equations along with some model systems as test
cases systematically. Then it outlines basic numerical approximations for derivatives and
techniques for the numerical solution of ordinary differential equations. Finally  more
complicated methods for approaching the pdes are derived.The authors describe major implicit
methods in detail and show how to handle homogeneous chemical reactions  even including coupled
and nonlinear cases. On this basis  more advanced techniques are briefly sketched and some of
the commercially available programs are discussed. In this way the reader is systematically
guided and can learn the tools for approaching his own electrochemical simulation problems.This
new fourth edition has been carefully revised  updated and extended compared to the previous
edition (Lecture Notes in Physics Vol. 666). It contains new material describing migration
effects  as well as arrays of ultramicroelectrodes. It is thus the most comprehensive and
didactic introduction to the topic of electrochemical simulation.

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