EAN: 9780306435492

THE CHEMICAL PHYSICS OF SURFACES - S R MORRISON...

of available information. Even more importantly  some authors who have contributed
substantially to an area may have been overlooked. For this I apologize. I have  however  not
attempted to trace techniques or observa tions historically  so there is no implication (unless
specified) that the authors referred to were or were not the originators of a given method or
observation. I would like to acknowledge discussions with co-workers at SFU for input relative
to their specialties  to acknowledge the help of students who have pointed out errors and
difficulties in the earlier presentation  and to acknowledge the infinite patience of my wife
Phyllis while I spent my sabbatical and more in libraries and punching computers. S. Roy
Morrison 0 1 Contents Notation XV 1. Introduction 1 1. 1. Surface States and Surface Sites . 1
1. 1. 1. The Chemical versus Electronic Representation of the Surface. 1 1. 1. 2. The Surface
State on the Band Diagram 4 1. 1. 3. The Fermi Energy in the Surface State Model. 6 1. 1. 4.
Need for Both Surface Site and Surface State Models 6 1. 2. Bonding of Foreign Species to the
Solid Surface 7 1. 2. 1. Types of Interaction. 7 1. 2. 2. The Chemical Bond . 10 1. 2. 3. Acid
and Basic Surface Sites on Solids . 13 1. 2. 4. Adsorbate Bonding on Various Solid Types. 16 1.
2. 5. Movement of Surface Atoms: Relaxation  Reconstruction  and Relocation .

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